产品说明
一般描述
Phenyl vinyl sulfoxide reacts with lithium enolates of ketones at -78℃ in THF to yield bicyclo[n.2.0]alkan-1-ols. It also reacts with in situ generated (dialkylamino)magnesium reagent to yield symmetrical β-(dialkylamino)dithioacetals. It participates as an acetylene equivalent in Diels-Alder reactions.
包装
5 g in glass bottle
基本信息
线性分子式 | C6H5SOCH=CH2 |
分子量 | 152.21 |
Beilstein | 2039218 |
EC 号 | 243-831-6 |
MDL编号 | MFCD00002086 |
PubChem化学物质编号 | 24852679 |
NACRES | NA.22 |
产品性质
测定 | 95% |
形式 | liquid |
折射率 | n |
bp | 93-95 ℃/0.2 mmHg (lit.) |
密度 | 1.139 g/mL at 25 ℃ (lit.) |
储存温度 | 2-8℃ |
SMILES string | C=CS(=O)c1ccccc1 |
InChI | 1S/C8H8OS/c1-2-10(9)8-6-4-3-5-7-8/h2-7H,1H2 |
InChI key | MZMJHXFYLRTLQX-UHFFFAOYSA-N |
Gene Information | human ... LOC129293(129293) |
安全信息
储存分类代码 | 10 - Combustible liquids |
WGK | WGK 3 |
闪点(F) | 230.0 °F - closed cup |
闪点(C) | 110 ℃ - closed cup |
个人防护装备 | Eyeshields, Gloves, multi-purpose combination respirator cartridge (US) |
Sigma-Aldrich