[<I>rac</I>-乙烯双(4,5,6,7-四氢-1-茚基)]二氯化锆(IV)

产品名称：

100163-29-9
Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV)
Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium
[rac-乙烯双(4,5,6,7-四氢-1-茚基)]二氯化锆(IV)

产品介绍：

产品说明

应用

Catalyst for:

Regiochemistry in Negishi carboaluminations
Polymerization of olefins
Diastereoselective intramolecular olefin alkylations
Asymmetric carbomagnesiation
Reduction of esters to alcohols
Enantioselective synthesis of allylic amines

包装

500 mg in glass bottle

基本信息

经验(实验)分子式	C₂₀H₂₄Cl₂Zr
分子量	426.53
MDL编号	MFCD00672123
PubChem化学物质编号	24877859
NACRES	NA.22

产品性质

质量水平	100
测定	97%
reaction suitability	core: zirconium reagent type: catalyst
mp	267-271 ℃ (lit.)
SMILES string	Cl[Zr]Cl.[CH]1[CH][C](CC[C]2[CH][CH][C]3CCCC[C]23)[C]4CCCC[C]14
InChI	1S/C20H24.2ClH.Zr/c1-3-7-19-15(5-1)9-11-17(19)13-14-18-12-10-16-6-2-4-8-20(16)18;;;/h9-12H,1-8,13-14H2;2*1H;/q;;;+2/p-2
InChI key	AKXWJOYQORUUHS-UHFFFAOYSA-L

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV)

Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium