CLAmP

产品名称：

CLAmP
Heller-Sarpong Reagent
N-Methoxy-N-methyl-1H-pyrrole-1-carboxamide

产品介绍：

产品说明

应用

The CLAmP (Carbonyl Linchpin N, O-dimethylhydroxylamine pyrrole) reagent, reported by Sarpong and Heller, is a useful building block for the efficient synthesis of unsymmetrical ketones. CLAmP shows high versatility based on compatibility with both highly reactive, thermally unstable nucleophiles as well as less reactive stable nucleophiles. It reacts with Grignard reagents to form the corresponding Weinreb amides.

包装

1 g in glass bottle

其他说明

One-pot Unsymmetrical Ketone Synthesis Employing a Pyrrole-Bearing Formal Carbonyl Dication Linchpin Reagent

基本信息

经验(实验)分子式	C₇H₁₀N₂O₂
分子量	154.17
PubChem化学物质编号	329769111

产品性质

形式	liquid
质量水平	100
折射率	n/D 1.510
密度	1.126 g/mL
储存温度	2-8℃
SMILES string	O=C(N(OC)C)N1C=CC=C1
InChI	1S/C7H10N2O2/c1-8(11-2)7(10)9-5-3-4-6-9/h3-6H,1-2H3
InChI key	NLSJGNBOCVXWHS-UHFFFAOYSA-N

安全信息

储存分类代码	10 - Combustible liquids
WGK	WGK 3
闪点(F)	230.0 °F
闪点(C)	110 ℃