产品说明
应用
RuCl2[(R)-(DM-SEGPHOS®)][(R,(R))-(DPEN)] can be used as a catalyst in the enantioselective preparation of chiral amino alcohols and their derivatives by asymmetric hydrogenation of various amino ketones using mild hydrogen pressure.
Takasago Ligands and Complexes for Asymmetric Reactions
包装
50, 100 mg in amber glass bottle
法律信息
与 Takasago 合作销售,仅用于研究目的。日本注册号 3148136,日本申请号 19970359654
SEGPHOS is a registered trademark of Takasago Intl. Corp.
基本信息
经验(实验)分子式 | C60H60Cl2N2O4P2Ru |
分子量 | 1107.05 |
MDL编号 | MFCD09753031 |
PubChem化学物质编号 | 329761484 |
NACRES | NA.22 |
产品性质
形式 | powder |
质量水平 | 100 |
储存温度 | 2-8℃ |
SMILES string | Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6OCOc6c5-c7c8OCOc8ccc7P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10 |
InChI | 1S/C46H44O4P2.C14H16N2.2ClH.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-24H,25-26H2,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1 |
InChI key | FOEKPXQPRAIJRW-ODQAEMFESA-L |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
Sigma-Aldrich