产品说明
应用
Trimethylphosphine is an electron-rich phosphine ligand used in the Mitsunobu reaction. It participates in the transformation of azides into carbamates, aziridines from azidoalcohols, iminophosphoranes and aza-Wittig reaction. This product is offered as a solution in 2-methyltetrahydrofuran for more convenient handling.
基本信息
| 线性分子式 | (CH3)3P |
| 分子量 | 76.08 |
| Beilstein | 969138 |
| MDL编号 | MFCD00008510 |
产品性质
| 形式 | liquid |
| 质量水平 | 100 |
| reaction suitability | reagent type: ligand reaction type: Mitsunobu Reaction reagent type: ligand reaction type: Wittig Reaction |
| 浓度 | 0.9 M in 2-methyltetrahydrofuran |
| 密度 | 0.838 g/mL |
| 官能团 | phosphine |
| SMILES string | CP(C)C |
| InChI | 1S/C3H9P/c1-4(2)3/h1-3H3 |
| InChI key | YWWDBCBWQNCYNR-UHFFFAOYSA-N |
安全信息
| 象形图 |    |
| 警示用语： | Danger |
| 危险声明 | H225 - H302 - H315 - H318 |
| 预防措施声明 | P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 |
| 危险分类 | Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 |
| 补充剂危害 | EUH019 |
| 储存分类代码 | 3 - Flammable liquids |
| WGK | WGK 3 |
| 闪点(F) | 5.0 °F |
| 闪点(C) | -15 ℃ |
Sigma-Aldrich
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