产品说明
一般描述
2-Naphthalenyl ester fluorosulfuric acid is a diaryl fluorosulfate (diaryl-OSO2F). It can be synthesized with 99% yield from the reaction between phenol and sulfuryl fluoride in the presence of triethylamine. It undergoes Suzuki-Miyaura reaction with aryl boronic acid in the presence of Pd(OAc)2 and Et3N to afford the corresponding biaryl derivative.
应用
The following aryl fluorosulfate can be utilized as a cross-coupling partner in Suzuki-Miyaura reactions. The standard reaction conditions for these palladium-catalyzed C-C bond formations are ligand-free and can be performed in water, at room temperature and are not air sensitive.
包装
500 mg in glass bottle
其他说明
Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates
基本信息
| 经验(实验)分子式 | C10H7FO3S |
| 分子量 | 226.22 |
| PubChem化学物质编号 | 329772675 |
| NACRES | NA.22 |
产品性质
| 形式 | powder |
| 质量水平 | 100 |
| SMILES string | O=S(OC1=CC=C2C(C=CC=C2)=C1)(F)=O |
| InChI | 1S/C10H7FO3S/c11-15(12,13)14-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H |
| InChI key | IJQQGAGYVGLLJL-UHFFFAOYSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Danger |
| 危险声明 | H314 |
| 预防措施声明 | P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
| 危险分类 | Skin Corr. 1B |
| 储存分类代码 | 8B - Non-combustible, corrosive hazardous materials |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
Sigma-Aldrich
m.cnreagent.com
