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Yu Borylation Ligand

Yu 硼化配体

品牌
Sigma-Aldrich
CAS
40335-00-0
货号
ALD00506
包装型号
规格纯度
≥95%
参考价格
215.93 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
-+
产品名称:
40335-00-0
Yu Borylation Ligand
Montanine
2,4-dimethoxyquinoline
Yu 硼化配体
产品介绍:

产品说明

一般描述

Yu Borylation Ligand, also referred to as 2,4-dimethoxyquinoline, has been developed by Professor Jin-Quan Yu and coworkers. 2,4-dimethoxyquinoline can be prepared by reacting 2,4-dichloroquinoline with sodium methoxide.

应用

The Yu Borylation Ligand in tandem with bis(pinacolato)diboron (Aldrich 473294) under palladium catalysis can promote direct borylation of C(sp3)-H bonds. Yu and coworkers have displayed this on both alanine-derived amides and cyclopropanes with directing group assistance from the Yu-Wasa Auxiliary (Aldrich 791806).
Yu Borylation Ligand (2,4-Dimethoxyquinoline) may be used as a starting reagent in the synthesis of 2,4 -dimethoxy-3-(3methylbut-2-enyl)quinoline and 4-methoxy-1H-quinolin-2-one. It may also be used in the preparation of isoprenyl derivatives.

包装

250 mg in glass bottle

其他说明

Ligand-Promoted Borylation of C(sp3)-H Bonds with Palladium(II) Catalysts

基本信息

经验(实验)分子式C11H11NO2
分子量189.21
MDL编号MFCD27950422
PubChem化学物质编号329772696
NACRESNA.22

产品性质

质量水平100
测定≥95%
形式powder
reaction suitabilityreagent type: ligand
reaction type: C-H Activation
SMILES stringCOC1=CC(OC)=NC2=CC=CC=C21
InChI1S/C11H11NO2/c1-13-10-7-11(14-2)12-9-6-4-3-5-8(9)10/h3-7H,1-2H3
InChI keyXSZBLRGKCBUWRJ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319 - H335
预防措施声明P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

Sigma-Aldrich

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