产品说明
一般描述
(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene, an enantiopure diene ligand developed by Carreira, is most commonly used in asymmetric catalysis. It is generally prepared from commercially available (R)-carvone.
应用
Carreira DOLEFIN Ligands
(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene is mainly useful for the stereoselective synthesis of diarylmethine stereogenic centers.
包装
100 mg in clear glass bottle
基本信息
经验(实验)分子式 | C22H30O |
分子量 | 310.47 |
MDL编号 | MFCD09265063 |
PubChem化学物质编号 | 329762875 |
产品性质
测定 | 97% |
形式 | liquid |
旋光性 | [α]/D −84±5°, c = 0.5 in chloroform |
reaction suitability | reaction type: click chemistry |
折射率 | n |
SMILES string | CO[C@@]1(C)C[C@@]2(C)C=C(Cc3ccccc3)[C@@H]1C=C2CC(C)C |
InChI | 1S/C22H30O/c1-16(2)11-19-13-20-18(12-17-9-7-6-8-10-17)14-21(19,3)15-22(20,4)23-5/h6-10,13-14,16,20H,11-12,15H2,1-5H3/t20-,21+,22-/m0/s1 |
InChI key | ACWLDJOHMGJACE-BDTNDASRSA-N |
安全信息
储存分类代码 | 12 - Non Combustible Liquids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
Sigma-Aldrich