(<i>S</i>)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

产品名称：

929097-92-7
(S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate
(11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d1′,2′f]-[1,3,2]-dioxaphosphepin 4-oxide
MacMillan TiPSY catalyst
(S)-3,3′-双(三苯甲硅烷基)-1,1′-联萘-2,2′-二酚磷酸酯
MacMillan TiPSY 催化剂
(11bS)-4-羟基-2,6-双(三苯甲硅烷基)二萘并-[2,1-d1′,2′f]-[1,3,2]-二恶磷环庚烷-4-氧化物

产品介绍：

产品说明

应用

(S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate can be used as a catalyst:

In the synthesis of 1,3-dioxolochroman skeletons by reacting 3-methyl-2-vinylindoles with ortho-quinone methides.
In the exo-selective cyclization of mupirocin methyl ester.
In the kinetic resolution of cyclic aliphatic syn-1,3-diols, which are used as valuable building blocks.

包装

100 mg in clear glass bottle

基本信息

经验(实验)分子式	C₅₆H₄₁O₄PSi₂
分子量	865.07
MDL编号	MFCD09265079
PubChem化学物质编号	24885544
NACRES	NA.22

产品性质

测定	96%
旋光性	[α]22/D +210°, c = 1 in chloroform
mp	188-193 ℃
SMILES string	OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)[Si](c6ccccc6)(c7ccccc7)c8ccccc8)[Si](c9ccccc9)(c%10ccccc%10)c%11ccccc%11
InChI	1S/C56H41O4PSi2/c57-61(58)59-55-51(62(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)60-61)63(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40H,(H,57,58)
InChI key	BDQOCXQVIFQJRK-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves