N-二[(R)-1-苯乙基]-[(S)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺

产品名称：

500997-70-6
(S)-SIPHOS-PE
N-Di[(R)-1-phenylethyl]-[(S)-1,1′-spirobiindane-7,7′-diyl]-phosphoramidite
(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1′, 7′-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine
N-二[(R)-1-苯乙基]-[(S)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺
(11aS)-(-)-10,11,12,13-四氢茚并[7,1-de:1′, 7′-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺

产品介绍：

产品说明

应用

(S)-SIPHOS-PE is a chiral spiro phosphoramidate ligand that can be used to synthesize:

Spiroindolenines by Pd-catalyzed intramolecular dearomative arylation of haloaryl-3-substituted indoles.
Enantioselective conjugate addition compound by Cu-catalyzed 1,4-addition of diethylzinc (Et₂Zn) to cyclic enones.
Octaketide natural products via rhodium-phosphoramidite catalyzed alkene hydroacylation.

包装

50, 250 mg in amber glass bottle

基本信息

经验(实验)分子式	C₃₃H₃₂NO₂P
分子量	505.59
MDL编号	MFCD08459342
PubChem化学物质编号	329762229
NACRES	NA.22

产品性质

测定	97%
形式	powder
旋光性	[α]22/D −65.0°, c = 1 in chloroform
mp	120-125 ℃
储存温度	−20℃
SMILES string	C[C@@H](N([C@H](C)c1ccccc1)P2Oc3cccc4CCC5(CCc6cccc(O2)c56)c34)c7ccccc7
InChI	1S/C33H32NO2P/c1-23(25-11-5-3-6-12-25)34(24(2)26-13-7-4-8-14-26)37-35-29-17-9-15-27-19-21-33(31(27)29)22-20-28-16-10-18-30(36-37)32(28)33/h3-18,23-24H,19-22H2,1-2H3/t23-,24-,33?/m1/s1
InChI key	ZXLQLIDJAURBDD-HRPAVAKOSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves