您好,欢迎来到试剂仪器网! [登录] [免费注册]
试剂仪器网
位置:首页 > 品牌 > Sigma-Aldrich > 1,2-双[(2R,5R)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)三氟甲磺酸铑(I)

1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

1,2-双[(2R,5R)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)三氟甲磺酸铑(I)

品牌
Sigma-Aldrich
CAS
136705-77-6
货号
698393
包装型号
规格纯度
参考价格
666.17 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
-+
产品名称:
136705-77-6
1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
(R,R)-Et-DUPHOS-Rh
1,2-双[(2R,5R)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)三氟甲磺酸铑(I)
产品介绍:

产品说明

应用

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:

  • Stereoselective synthesis of δ-amino acid derivatives via asymmetric hydrogenation of acetylaminopentenoic acid derivatives
  • Stereoselective synthesis of manzacidins A and C via stereoselective hydrogenation
  • Stereoselective synthesis of tetracyclic core of manzamine A via Rh-catalyzed asymmetric hydrogenation, diastereoselective Diels-Alder reaction, Eschenmoser-Tanabe fragmentation, Chang′s amide formation, and Hofmann rearrangement
  • Asymmetric preparation of chiral Cbz-aminodifluorobutyric acid Me ester and its analogs
  • Biphasic catalytic hydrogenations in ionic liquids with addition of water as a second solvent
  • Preparation of cyclobutane-containing amino acids via asymmetric hydrogenations of cyclobutyl enamides
  • Asymmetric preparation of both enantiomers of (dimethoxycoumaryl)alanine as suitable fluorescent peptide labels

包装

50, 250 mg in amber glass bottle

法律信息

与 Kanata Chemical Technologies Inc. 联合销售,仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售,此许可不包括利用这些化合物制备在制药领域销售的产品的权利。

基本信息

经验(实验)分子式C31H48F3O3P2RhS
分子量722.62
MDL编号MFCD00269860
PubChem化学物质编号329761250
NACRESNA.22

产品性质

形式powder
SMILES string[Rh+].[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1.CC[C@@H]2CC[C@@H](CC)P2c3ccccc3P4[C@H](CC)CC[C@H]4CC
InChI1S/C22H36P2.C8H12.CHF3O3S.Rh/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h9-12,17-20H,5-8,13-16H2,1-4H3;1-2,7-8H,3-6H2;(H,5,6,7);/q;;;+1/p-1/b;2-1-,8-7-;;/t17-,18-,19-,20-;;;/m1.../s1
InChI keyHZLILTNLWVOBFS-KYOOHHHUSA-M

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves

Sigma-Aldrich

推荐产品