1,2-双[(2<I>S</I>,5<I>S</I>)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I)

产品名称：

213343-64-7
1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
(S,S)-Et-DUPHOS-Rh
1,2-双[(2S,5S)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I)

产品介绍：

产品说明

应用

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:

Preparation of a key unit B precursor of cryptophycins via Horner-Wadsworth-Emmons reaction and asymmetric hydrogenation
Preparation of constrained phenylalanine analogs via Heck reaction followed by asymmetric hydrogenation and cyclization steps
Enantioselective preparation of N-benzyloxy-β-amino acid Me esters by hydrogenation of α-(benzyloxyaminomethyl)acrylate stereoisomers
Preparation of fluoro amino acids as synthons for potent macrocyclic HCV NS3 protease inhibitors
Stereoselective preparation of triply isotope-labeled Ser, Cys, and Ala
Preparation of β-amino acids from asymmetric hydrogenation of α-(aminomethyl)acrylates
Asymmetric hydrogenation of a-primary and secondary amino ketones and asymmetric synthesis of (-)-arbutamine and (-)-denopamine

包装

50, 250 mg in amber glass bottle

法律信息

与 Kanata Chemical Technologies Inc. 联合销售，仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售，此许可不包括利用这些化合物制备在制药领域销售的产品的权利。

基本信息

经验(实验)分子式	C₃₀H₄₈BF₄P₂Rh
分子量	660.36
PubChem化学物质编号	329761249
NACRES	NA.22

产品性质

形式	powder
SMILES string	[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CC[C@H]2CC[C@H](CC)P2c3ccccc3P4[C@@H](CC)CC[C@@H]4CC
InChI	1S/C22H36P2.C8H12.BF4.Rh/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-12,17-20H,5-8,13-16H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t17-,18-,19-,20-;;;/m0.../s1
InChI key	DSYBEQKPSKLNMC-ZCTOJWETSA-N

安全信息

储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)