产品说明
一般描述
3-Methyl-3-(2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl)-1,5-dioxaspiro[5.5]undecane-2,4-dione is a substituted Meldrum′s acid derivative. It can be prepared by reacting octafluorotoluene with 3-methyl-1,5-dioxaspiro[5.5]undecane-2,4- dione.
应用
This compound undergoes cycloreversion to form the fluoro(hetero)aryl ketene, which undergoes efficient coupling with nucleophiles and allows rapid incorporation of highly fluorinated α-fluoro(hetero)aryl acetic acid derivatives.
包装
250 mg in glass bottle
其他说明
Selective Perfluoro- and Polyfluoroarylation of Meldrum′s Acid
基本信息
经验(实验)分子式 | C17H13F7O4 |
分子量 | 414.27 |
MDL编号 | MFCD28359686 |
PubChem化学物质编号 | 329769148 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | ≥95% |
形式 | powder |
储存温度 | 2-8℃ |
SMILES string | FC1=C(F)C(C(F)(F)F)=C(F)C(F)=C1C2(C)C(OC3(CCCCC3)OC2=O)=O |
InChI | 1S/C17H13F7O4/c1-15(13(25)27-16(28-14(15)26)5-3-2-4-6-16)7-9(18)11(20)8(17(22,23)24)12(21)10(7)19/h2-6H2,1H3 |
InChI key | XZOHIXYQGCQJFM-UHFFFAOYSA-N |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
Sigma-Aldrich