产品说明
一般描述
3-Propyl-3-(2,3,5,6-tetrafluoro-4-nitrophenyl)-1,5-dioxaspiro[5.5]undecane-2,4-dione can be synthesized from pentafluoronitrobenzene, 3-propyl-1,5-dioxaspiro[5.5]undecane-2,4-dione, N,N-diisopropylethylamine and CH3CN.
应用
This compound undergoes cycloreversion to form the fluoro(hetero)aryl ketene, which undergoes efficient coupling with nucleophiles and allows rapid incorporation of highly fluorinated α-fluoro(hetero)aryl acetic acid derivatives.
包装
250 mg in glass bottle
其他说明
Selective Perfluoro- and Polyfluoroarylation of Meldrum′s Acid
基本信息
经验(实验)分子式 | C18H17F4NO6 |
分子量 | 419.32 |
MDL编号 | MFCD28359688 |
PubChem化学物质编号 | 329769141 |
产品性质
形式 | powder |
质量水平 | 100 |
储存温度 | 2-8℃ |
SMILES string | FC1=C(F)C([N+]([O-])=O)=C(F)C(F)=C1C2(CCC)C(OC3(CCCCC3)OC2=O)=O |
InChI | 1S/C18H17F4NO6/c1-2-6-18(9-10(19)12(21)14(23(26)27)13(22)11(9)20)15(24)28-17(29-16(18)25)7-4-3-5-8-17/h2-8H2,1H3 |
InChI key | JWAHHCQJIGIGMQ-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 |
预防措施声明 | P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
Sigma-Aldrich