二-1-金刚烷基(4″-丁基-2″,3″,5″,6″-四氟-2′,4′,6′-三异丙基-2-甲氧基-间三联苯)膦

产品名称：

1805783-60-1
AlPhos
Di-1-adamantyl(4″-butyl-2″,3″,5″,6″-tetrafluoro-2′,4′,6′-triisopropyl-2-methoxy-meta-terphenyl)phosphine
二-1-金刚烷基(4″-丁基-2″,3″,5″,6″-四氟-2′,4′,6′-三异丙基-2-甲氧基-间三联苯)膦

产品介绍：

产品说明

应用

AlPhos is a biaryl monophosphine ligand that can be used:

In the Pd-catalyzed Buchwald-Hartwig cross-coupling reactions.
To synthesize highly regioselective aryl fluorides by Pd-catalyzed fluorination of a variety of activated aryl and heteroaryl triflates and bromides.
To prepare aryl thioethers by C–S cross-coupling of thiols with aromatic electrophile in the presence of palladium catalyst.

包装

100 mg in glass bottle

基本信息

经验(实验)分子式	C₅₂H₆₇F₄OP
分子量	815.06
PubChem化学物质编号	329768101

产品性质

质量水平	100
测定	≥95%
形式	powder
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand reaction type: Cross Couplings
mp	218-223 ℃
官能团	phosphine
储存温度	−20℃
InChI	1S/C52H67F4OP/c1-9-10-12-38-46(53)48(55)45(49(56)47(38)54)44-40(29(4)5)21-39(28(2)3)43(42(44)30(6)7)37-13-11-14-41(57-8)50(37)58(51-22-31-15-32(23-51)17-33(16-31)24-51)52-25-34-18-35(26-52)20-36(19-34)27-52/h11,13-14,21,28-36H,9-10,12,15-20,22-27H2,1-8H3/t31-,32+,33?,34-,35+,36?,51+,52?,58?
InChI key	ALWIRDZSIXWCBO-VABCSHEKSA-N

安全信息

储存分类代码	11 - Combustible Solids
WGK	WGK 3