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Bis(3,5-dimethylphenyl)phosphine

双(3,5-二甲苯基)磷

品牌
Sigma-Aldrich
CAS
71360-06-0
货号
695157
包装型号
规格纯度
参考价格
1997.77 *本价格含增值税费
促销
服务
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数量
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产品名称:
71360-06-0
Bis(3,5-dimethylphenyl)phosphine
双(3,5-二甲苯基)磷
产品介绍:

产品说明

应用

Bis(3,5-dimethylphenyl)phosphine can be used as a reactant to prepare:

  • Iron(II) chiral diimine diphosphine complexes as catalysts for the asymmetric transfer hydrogenation of ketones.
  • The complex of iridium with biphenol phosphite-phosphine bidentate ligand as an asymmetric catalyst for the hydrogenation of N-arylimines.
  • Chiral phosphines with excellent stereoselectivity by 1, 4 addition reaction with α,β-unsaturated aldehydes using a palladium catalyst.

包装

100, 500 mg in glass bottle

法律信息

Kanata Chemical Technologies, Inc. 产品

基本信息

经验(实验)分子式C16H19P
分子量242.30
MDL编号MFCD01074629
PubChem化学物质编号329761721

产品性质

质量水平100
形式liquid
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
折射率n20/D 1.599
密度1.017 g/mL at 25 ℃
官能团phosphine
SMILES stringCc1cc(C)cc(Pc2cc(C)cc(C)c2)c1
InChI1S/C16H19P/c1-11-5-12(2)8-15(7-11)17-16-9-13(3)6-14(4)10-16/h5-10,17H,1-4H3
InChI keyGPFIUEZTNRNFGD-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
危险分类Acute Tox. 4 Oral
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)230.0 °F
闪点(C)> 110 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Sigma-Aldrich

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