<i>cis</i>-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride

产品名称：

1594113-05-9
cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride
cis-((S)-BINAP)Ni(o-tolyl)Cl

产品介绍：

产品说明

应用

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)₂, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

其他说明

Technology Spotlight: Jamison Nickel (II) Precatalysts
A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

法律信息

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

基本信息

经验(实验)分子式	C₅₁H₃₉ClNiP₂
分子量	807.95

产品性质

质量水平	100
形式	powder or solid
reaction suitability	core: nickel reagent type: catalyst
mp	>300 ℃
SMILES string	Cl[Ni]1(P(C2=C([H])C([H])=C([H])C([H])=C2[H])(C3=C([H])C([H])=C([H])C([H])=C3[H])C(C([H])=C4[H])=[C@@]([C@@]5=C(P1(C6=C([H])C([H])=C([H])C([H])=C6[H])C7=C([H])C([H])=C([H])C([H])=C7[H])C([H])=C([H])C8=C5C([H])=C([H])C([H])=C8[H])C9=C4C([H])=C([H])C([H])=C

安全信息

储存分类代码	4.1B - Flammable solid hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride

cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride