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位置:首页 > 品牌 > Sigma-Aldrich > Endo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine

Endo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine

品牌
Sigma-Aldrich
货号
798436
包装型号
规格纯度
参考价格
829.26 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
-+
产品名称:
Endo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine
(1S,4S,5S)-5-(naphthalen-1-yl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane
产品介绍:

产品说明

应用

The bicyclic, chiral phosphine was developed by the Kwon Research Group. Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.

包装

100 mg in glass bottle

其他说明

Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-Pyrrolines

Technology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from Hydroxyproline

Aldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations

基本信息

经验(实验)分子式C22H22NO2PS
分子量395.45
PubChem化学物质编号329768649
NACRESNA.22

产品性质

形式powder
质量水平100
储存条件under inert gas
储存温度2-8℃
SMILES stringO=S(N1C[C@H]2[P@@](C3=CC=CC4=C3C=CC=C4)C[C@@H]1C2)(C5=CC=C(C)C=C5)=O
InChI1S/C22H22NO2PS/c1-16-9-11-20(12-10-16)27(24,25)23-14-19-13-18(23)15-26(19)22-8-4-6-17-5-2-3-7-21(17)22/h2-12,18-19H,13-15H2,1H3
InChI keyRGHUOMJULXTHPX-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

Sigma-Aldrich

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