Exo-Phenyl Kwon [2.2.1]双环膦

产品名称：

Exo-Phenyl Kwon [2.2.1] Bicyclic Phosphine
(1S,4S,5R)-5-(phenyl)-2-tosyl-2-aza-5-phosphabicyclo[2.2.1]heptane
Exo-Phenyl Kwon [2.2.1]双环膦

产品介绍：

产品说明

应用

The bicyclic, chiral phosphine was developed by the Kwon Research Group.Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.

包装

100 mg in glass bottle

其他说明

Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-Pyrrolines

Technology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from Hydroxyproline

Aldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations

基本信息

经验(实验)分子式	C₁₈H₂₀NO₂PS
分子量	345.40
PubChem化学物质编号	329768644
NACRES	NA.22

产品性质

质量水平	100
测定	95% (HPLC)
形式	powder
储存条件	under inert gas
mp	158-162 ℃
储存温度	2-8℃
SMILES string	CC1=CC=C(S(N2C[C@@]3([H])[P@](C4=CC=CC=C4)C[C@]2([H])C3)(=O)=O)C=C1
InChI	1S/C18H20NO2PS/c1-14-7-9-18(10-8-14)23(20,21)19-12-17-11-15(19)13-22(17)16-5-3-2-4-6-16/h2-10,15,17H,11-13H2,1H3
InChI key	BWXYDSDVFPJTFY-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H302
预防措施声明	P301 + P312 + P330
危险分类	Acute Tox. 4 Oral
储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable