Ru(4,4-dicarboxylic acid-2,2′-bipyridine)(4,4′-bis(p-hexyloxystyryl)-2,2-bipyridine)(NCS)<SUB>2</SUB>

产品名称：

847665-45-6
K19 Dye
K 19 sensitizer
Ru(4,4-dicarboxylic acid-2,2′-bipyridine)(4,4′-bis(p-hexyloxystyryl)-2,2-bipyridine)(NCS)₂

产品介绍：

产品说明

一般描述

K19 Dye is an amphiphilic ruthenium sensitizer with a good molar extinction coefficient, which remains stable under thermal stress and light soaking. It can be synthesized by forming a reaction mixture of 4,4′-Bis(p-hexyloxystyryl)-2,2′-bipyridine, dichloro(p-cymene)ruthenium(II) dimer, and 4,4′-dicarboxylic acid-2,2′-bipyridine. It shows an overall power conversion efficiency (PCE) of 11% and can be used as an active material in electrochemical applications.

应用

K19 Dye is an organo-metallic dye that can be used as a photosensitizing material in the fabrication of dye sensitized solar cells (DSSCs). It shows a short circuit photocurrent density of 15.1 mA/cm², an open circuit voltage of 747 mV and a fill factor of 0.69.
Electron transfer from K-19 dye to the conduction band of Titania is completed within 20 fs while charge recombination has a half-life of 800 μs. The high extinction coefficient of this sensitizer enable realization of a new generation thin-film dye-sensitized solar cells (DSCs) yielding high conversion efficiency at full sunlight, even with viscous electrolytes based on ionic liqs. or nonvolatile solvents, making solar cell devices exhibit excellent stability under light soaking.

包装

250 mg in glass insert

法律信息

Dyesol^® Product. Dyesol is a registered trademark of Dyesol Ltd.
Dyesol is a registered trademark of Greatcell Solar

基本信息

PubChem化学物质编号	329768273
NACRES	NA.23

产品性质

质量水平	100
测定	85% (HPLC)
形式	powder (black)
mp	>300 ℃
λ_max	536, 357, 311 nm at 0.02 mM in DMF (lit.)
SMILES string	OC(C1=CC(C2=CC(C(O)=O)=CC=N2)=NC=C1)=O.S=C=N[Ru]N=C=S.CCCCCCOC(C=C3)=CC=C3/C=C/C4=CC=NC(C5=NC=CC(/C=C/C6=CC=C(OCCCCCC)C=C6)=C5)=C4
InChI	1S/C38H44N2O2.C12H8N2O4.2CNS.Ru/c1-3-5-7-9-27-41-35-19-15-31(16-20-35)11-13-33-23-25-39-37(29-33)38-30-34(24-26-40-38)14-12-32-17-21-36(22-18-32)42-28-10-8-6-4-2;15-11(16)7-1-3-13-9(5-7)10-6-8(12(17)18)2-4-14-10;22-1-3;/h11-26,29-30H,3-10,27-28H2,1-2H3;1-6H,(H,15,16)(H,17,18);;;/q;;2-1;+2/b13-11+,14-12+;;;;
InChI key	HBARXZGSEMEPLK-BPSJQPAOSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H317 - H319 - H335
预防措施声明	P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

K19 Dye

Ru(4,4-dicarboxylic acid-2,2′-bipyridine)(4,4′-bis(p-hexyloxystyryl)-2,2-bipyridine)(NCS)2

Ru(4,4-dicarboxylic acid-2,2′-bipyridine)(4,4′-bis(p-hexyloxystyryl)-2,2-bipyridine)(NCS)₂