<I>R</I>-(叔丁基甲基膦-二叔丁基膦甲烷)-η<SUB>4</SUB>-(1,5-环辛二烯)四氟硼酸铑(I)

产品名称：

R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η₄-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
R-[Rh cod TCFP]BF₄
(R)-TCFP-Rh
TCFP
R-(叔丁基甲基膦-二叔丁基膦甲烷)-η₄-(1,5-环辛二烯)四氟硼酸铑(I)
R[Rh(cod)TCFP]BF₄

产品介绍：

产品说明

应用

R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can be used:

In the asymmetric reduction of amines, ketones and unsaturated acids.
As a hydrogenation catalyst in the preparation of diastereomers of trifluorovaline.
As a catalyst in the olefin asymmetric hydrogenation.

包装

100 mg in clear glass bottle

法律信息

与 Johnson Matthey 联合销售，仅供研究目的。

基本信息

经验(实验)分子式	C₂₂H₄₄P₂Rh
分子量	473.44
MDL编号	MFCD11973806
PubChem化学物质编号	329762467
NACRES	NA.22

产品性质

质量水平	100
测定	96%
形式	solid
mp	171-177 ℃
储存温度	2-8℃
SMILES string	[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CP(CP(C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI	1S/C14H32P2.C8H12.BF4.Rh/c1-12(2,3)15(10)11-16(13(4,5)6)14(7,8)9;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11H2,1-10H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t15-;;;/m1.../s1
InChI key	CQCAQRWECWCUBU-JMJDVLNDSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 2
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)

R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

R-(叔丁基甲基膦-二叔丁基膦甲烷)-η4-(1,5-环辛二烯)四氟硼酸铑(I)

R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η₄-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

R-(叔丁基甲基膦-二叔丁基膦甲烷)-η₄-(1,5-环辛二烯)四氟硼酸铑(I)