SLAP 2,3-Bicyclo-(3,4-THF) <i>N</i>-BnPip Reagent

产品名称：

SLAP 2,3-Bicyclo-(3,4-THF) N-BnPip Reagent
trans-N³-Benzyl-N³-((trimethylsilyl)methyl)tetrahydrofuran-3,4-diamine

产品介绍：

产品说明

应用

Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)₂dtbbpy]PF₆ (747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.

包装

500 mg in amber glass bottle

其他说明

Technology Spotlight: SLAP Reagents for Piperazine Synthesis
Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

基本信息

经验(实验)分子式	C₁₅H₂₆N₂OSi
分子量	278.47
NACRES	NA.22

产品性质

质量水平	100
测定	≥95%
形式	liquid
折射率	n/D 1.520
密度	1.000 g/mL
储存温度	−20℃

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	10 - Combustible liquids
WGK	WGK 3