SLAP 5-TMS TM

产品名称：

2084112-39-8
SLAP 5-TMS TM
2-((Bis(trimethylsilyl)methyl)thio)ethanamine

产品介绍：

产品说明

应用

When used with aliphatic or aromatic aldehydes, this silicon amine protocol SLAP reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)₂dtbbpy]PF₆ (747769) is used with a recommended starting combination of Lewis acids Bi(OTf)₃ (633305) and Cu(OTf)₂ (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions.

包装

500 mg in amber glass bottle

其他说明

Technology Spotlight: SLAP Reagents for Piperazine Synthesis
Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

基本信息

经验(实验)分子式	C₉H₂₅NSSi₂
分子量	235.54
NACRES	NA.22

产品性质

质量水平	100
测定	≥95%
形式	suspension
密度	0.9126
储存温度	2-8℃
SMILES string	NCCSC([Si](C)(C)C)[Si](C)(C)C

安全信息

象形图
警示用语：	Danger
危险声明	H225
预防措施声明	P210 - P370 + P378 - P403 + P235
危险分类	Flam. Liq. 2
储存分类代码	3 - Flammable liquids
WGK	WGK 3
闪点(F)	30.0 °F
闪点(C)	-1.11 ℃