产品说明
一般描述
The product is a substituted SnAP [Sn(tin) amino protocol] reagent. SnAP reagents are air and moisture stable.
应用
SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group
包装
500 mg in glass bottle
其他说明
Technology spotlight: SnAP Reagents
Professor product portal: Jeffrey Bode Research Group
SnAP Reagents for the Synthesis of Piperazines and Morpholines
SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes
SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles
Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles
基本信息
经验(实验)分子式 | C23H48N2O3Sn |
分子量 | 519.35 |
PubChem化学物质编号 | 329768849 |
NACRES | NA.22 |
产品性质
形式 | liquid |
质量水平 | 100 |
折射率 | n |
密度 | 1.122 |
储存温度 | −20℃ |
SMILES string | CCCC[Sn](CCCC)(COCC1(CN(C(OC(C)(C)C)=O)CC1)N)CCCC |
InChI | 1S/C11H21N2O3.3C4H9.Sn/c1-10(2,3)16-9(14)13-6-5-11(12,7-13)8-15-4;3*1-3-4-2;/h4-8,12H2,1-3H3;3*1,3-4H2,2H3; |
InChI key | JLZWEXDNLRNRBE-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H301 - H315 - H319 - H335 |
预防措施声明 | P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 |
危险分类 | Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects |
WGK | WGK 3 |
Sigma-Aldrich