<i>trans</i>-Bis(methyldiphenylphosphine)(2-methylphenyl)nickel(II) chloride

产品名称：

1594112-89-6
trans-Bis(methyldiphenylphosphine)(2-methylphenyl)nickel(II) chloride
trans-(PPh₂Me)₂Ni(o-tolyl)Cl

产品介绍：

产品说明

应用

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)₂, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

其他说明

Technology Spotlight: Jamison Nickel (II) Precatalysts
A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

法律信息

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

基本信息

经验(实验)分子式	C₃₃H₃₃ClNiP₂
分子量	585.71

产品性质

质量水平	100
形式	powder or solid
reaction suitability	core: nickel reagent type: catalyst
mp	152-157 ℃
SMILES string	Cl[Ni](PC([H])([H])[H])(P(C1=C([H])C([H])=C([H])C([H])=C1[H])(C2=C([H])C([H])=C([H])C([H])=C2[H])C([H])([H])[H])C3=C(C([H])([H])[H])C([H])=C([H])C([H])=C3[H].[H]C4=C(C5=C([H])C([H])=C([H])C([H])=C5[H])C([H])=C([H])C([H])=C4[H]

安全信息

储存分类代码	4.1B - Flammable solid hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

trans-Bis(methyldiphenylphosphine)(2-methylphenyl)nickel(II) chloride