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位置:首页 > 品牌 > Sigma-Aldrich > trans-Bis(methyldiphenylphosphine)(2-methylphenyl)nickel(II) chloride

trans-Bis(methyldiphenylphosphine)(2-methylphenyl)nickel(II) chloride

品牌
Sigma-Aldrich
CAS
1594112-89-6
货号
901169
包装型号
规格纯度
参考价格
793.35 *本价格含增值税费
促销
服务
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数量
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产品名称:
1594112-89-6
trans-Bis(methyldiphenylphosphine)(2-methylphenyl)nickel(II) chloride
trans-(PPh2Me)2Ni(o-tolyl)Cl
产品介绍:

产品说明

应用

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.

其他说明

  • Technology Spotlight: Jamison Nickel (II) Precatalysts
  • A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

法律信息

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

基本信息

经验(实验)分子式C33H33ClNiP2
分子量585.71

产品性质

质量水平100
形式powder or solid
reaction suitabilitycore: nickel
reagent type: catalyst
mp152-157 ℃
SMILES stringCl[Ni](PC([H])([H])[H])(P(C1=C([H])C([H])=C([H])C([H])=C1[H])(C2=C([H])C([H])=C([H])C([H])=C2[H])C([H])([H])[H])C3=C(C([H])([H])[H])C([H])=C([H])C([H])=C3[H].[H]C4=C(C5=C([H])C([H])=C([H])C([H])=C5[H])C([H])=C([H])C([H])=C4[H]

安全信息

储存分类代码4.1B - Flammable solid hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

Sigma-Aldrich

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