<i>trans</i>-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride

产品名称：

1594112-87-4
trans-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride
trans-(PBn₃)₂Ni(o-tolyl)Cl

产品介绍：

产品说明

应用

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)_2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

其他说明

Technology Spotlight: Jamison Nickel (II) Precatalysts
A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

法律信息

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

基本信息

经验(实验)分子式	C₄₉H₄₉ClNiP₂
分子量	794.01

产品性质

质量水平	100
测定	95%
形式	powder or solid
reaction suitability	reagent type: catalyst
mp	200-205 ℃
SMILES string	Cl[Ni](C1=C(C)C=CC=C1)(P(CC2=CC=CC=C2)(CC3=CC=CC=C3)CC4=CC=CC=C4)P(CC5=CC=CC=C5)(CC6=CC=CC=C6)CC7=CC=CC=C7

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

trans-Bis(tribenzylphosphine)(2-methylphenyl)nickel(II) chloride