<i>trans</i>-Bis(triethylphosphine)(2,4,6-trimethylphenyl)nickel(II) bromide

产品名称：

69456-30-0
trans-Bis(triethylphosphine)(2,4,6-trimethylphenyl)nickel(II) bromide
trans-(PEt₃)₂Ni(mesityl)Br

产品介绍：

产品说明

应用

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)₂, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

其他说明

Technology Spotlight: Jamison Nickel (II) Precatalysts
A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes

法律信息

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

基本信息

经验(实验)分子式	C₂₁H₄₁BrNiP₂
分子量	494.10

产品性质

质量水平	100
测定	≥95%
形式	powder or solid
reaction suitability	core: nickel reagent type: catalyst
mp	159-164 ℃
SMILES string	Br[Ni](C1=C(C)C=C(C)C=C1C)(P(CC)(CC)CC)P(CC)(CC)CC

安全信息

储存分类代码	4.1B - Flammable solid hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

trans-Bis(triethylphosphine)(2,4,6-trimethylphenyl)nickel(II) bromide