((1R,3R,3′R)-3,3′-diethyl-3H,3′H-1,1′-spirobi[isobenzofuran]-7,7′-diyl)bis(diphenylphosphane)

产品名称：

(R,R,R)-SPIRAP
(R)-CrabPhos
((1R,3R,3′R)-3,3′-diethyl-3H,3′H-1,1′-spirobi[isobenzofuran]-7,7′-diyl)bis(diphenylphosphane)

产品介绍：

产品说明

应用

(R,R,R)-SPIRAP is a chiral C₂-symmetric spiroketal-containing ligand developed in the Nagorny lab for asymmetric catalysis. It can be used in variety of stereoselective transformations, including: Ir-catalyzed hydroarylation, Pd-catalyzed allylic alkylation, Pd-catalyzed Heck couplings, and Rh-catalyzed hydrogenation.

其他说明

Design, Synthesis, and Application of Chiral C₂-Symmetric Spiroketal-Containing Ligands in Transition-Metal Catalysis

基本信息

经验(实验)分子式	C₄₃H₃₈O₂P₂
分子量	648.71

产品性质

测定	≥95%
形式	powder or crystals
reaction suitability	reagent type: ligand reaction type: Asymmetric synthesis
mp	226-228 ℃
SMILES string	CC[C@@H](O1)C2=C([C@@]1(O[C@@H]3CC)C4=C3C=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)C(P(C7=CC=CC=C7)C8=CC=CC=C8)=CC=C2

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable