(<i>S</i>)-<i>N</i>-Butyl-1-[(2-hydroxybenzyl)-<sc>L</sc>-valyl]pyrrolidine-2-carboxamide

产品名称：

1613249-60-7
(S)-N-Butyl-1-[(2-hydroxybenzyl)-L-valyl]pyrrolidine-2-carboxamide
Yoon Syn-[2+2]-Photocycloaddition Ligand

产品介绍：

产品说明

一般描述

(S)-N-Butyl-1-[(2-hydroxybenzyl)-L-valyl]pyrrolidine-2-carboxamide is a secondary amine ligand. It act as a Lewis acid co-catalyst for [2+2] cycloaddition on complexation with Eu(OTf)₃ (europium(III)triflate).

应用

Chiral ligand for the asymmetric [2+2] cycloaddition of enones by photoredox catalysis.

包装

50 mg in glass bottle

其他说明

A Dual-Catalysis Approach to Enantioselective [2 + 2] Photocycloadditions Using Visible Light

基本信息

经验(实验)分子式	C₂₁H₃₃N₃O₃
分子量	375.51
PubChem化学物质编号	329768672
NACRES	NA.22

产品性质

形式	liquid
质量水平	100
储存温度	2-8℃
SMILES string	OC1=C(CN[C@@H](C(C)C)C(N2[C@H](C(NCCCC)=O)CCC2)=O)C=CC=C1
InChI	1S/C21H33N3O3/c1-4-5-12-22-20(26)17-10-8-13-24(17)21(27)19(15(2)3)23-14-16-9-6-7-11-18(16)25/h6-7,9,11,15,17,19,23,25H,4-5,8,10,12-14H2,1-3H3,(H,22,26)/t17-,19-/m0/s1
InChI key	YETNAJXRRQTUPV-HKUYNNGSSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H302
预防措施声明	P301 + P312 + P330
危险分类	Acute Tox. 4 Oral
储存分类代码	12 - Non Combustible Liquids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable