产品说明
一般描述
MacMillan imidazolidinone organocatalysts are metal-free chiral catalysts widely used in enantioselective organic transformations. These organocatalysts are non-toxic, low cost, and robust in simple reaction conditions because of their insensitivity to air and moisture.
应用
MacMillan Imidazolidinone organocatalysts can be used to catalyze various organocatalytic transformation reactions such as 1,3-dipolar cycloadditions, Diels–Alder reaction, Friedel-Crafts alkylations, α-chlorinations, α-fluorinations, and intramolecular Michael reactions to access a high level of enantioselective products. It can also be used in enantioselective photocatalytic reactions, hydride reduction, and Mukaiyama-Michael reaction.
包装
1 kit in glass bottle
法律信息
适用美国专利 6,369,243 和相关专利。仅供研究使用。
基本信息
| eCl@ss | 32161000 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
组份列表
组份可单独销售
| 货号 | 组份 |
| 569763 | (5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride, 97% 500 mg |
| 661902 | (S)-(+)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid, 96% 500 mg |
| 663085 | (5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone dichloroacetic acid, 97% 500 mg |
| 663107 | (2S,5S)-(−)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone, 97% 500 mg |
| 668540 | (2S,5S)-(–)-5-Benzyl-3-methyl-2-(5-methyl-2-furyl)-4-imidazolidinone, 95% 250 mg |
安全信息
| 象形图 |   |
| 警示用语： | Danger |
| 危险声明 | H301 - H315 - H318 - H335 |
| 预防措施声明 | P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 + P310 |
| 危险分类 | Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
Sigma-Aldrich
m.cnreagent.com
