产品说明
一般描述
1-Bromo-2,4,6-tri-tert-butylbenzene (2,4,6-tri-tert-butylbromobenzene) is a hindered aryl bromide. 1-Bromo-2,4,6-tri-tert-butylbenzene on reaction with phenylboronic acid yields α,α-dimethyl-β-phenyl hydrostyrene.
应用
1-Bromo-2,4,6-tri-tert-butylbenzene was used in the synthesis of bulky biarylphosphine ligand. This ligand was reported to participate in the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions. It was used to investigate the effect on oligomerization of increased steric bulk in dimethylindium(
包装
1, 5 g in glass bottle
基本信息
| 线性分子式 | [(CH3)3C]3C6H2Br |
| 分子量 | 325.33 |
| Beilstein | 1913257 |
| MDL编号 | MFCD00191861 |
| PubChem化学物质编号 | 24865424 |
| NACRES | NA.22 |
产品性质
| 测定 | 97% |
| mp | 168-173 ℃ (lit.) |
| SMILES string | CC(C)(C)c1cc(c(Br)c(c1)C(C)(C)C)C(C)(C)C |
| InChI | 1S/C18H29Br/c1-16(2,3)12-10-13(17(4,5)6)15(19)14(11-12)18(7,8)9/h10-11H,1-9H3 |
| InChI key | JOKZWHPYNRDCOA-UHFFFAOYSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H315 - H319 - H335 |
| 预防措施声明 | P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
Sigma-Aldrich
m.cnreagent.com
