1-溴-2,4,6-三叔丁基苯

产品名称：

3975-77-7
1-Bromo-2,4,6-tri-tert-butylbenzene
1-溴-2,4,6-三叔丁基苯

产品介绍：

产品说明

一般描述

1-Bromo-2,4,6-tri-tert-butylbenzene (2,4,6-tri-tert-butylbromobenzene) is a hindered aryl bromide. 1-Bromo-2,4,6-tri-tert-butylbenzene on reaction with phenylboronic acid yields α,α-dimethyl-β-phenyl hydrostyrene.

应用

1-Bromo-2,4,6-tri-tert-butylbenzene was used in the synthesis of bulky biarylphosphine ligand. This ligand was reported to participate in the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions. It was used to investigate the effect on oligomerization of increased steric bulk in dimethylindium(III) chalcogenolates. It may be used to form α,α-dimethyl-β-phenyl hydrostyrene by reacting with phenylboronic acid.

包装

1, 5 g in glass bottle

基本信息

线性分子式	[(CH₃)₃C]₃C₆H₂Br
分子量	325.33
Beilstein	1913257
MDL编号	MFCD00191861
PubChem化学物质编号	24865424
NACRES	NA.22

产品性质

测定	97%
mp	168-173 ℃ (lit.)
SMILES string	CC(C)(C)c1cc(c(Br)c(c1)C(C)(C)C)C(C)(C)C
InChI	1S/C18H29Br/c1-16(2,3)12-10-13(17(4,5)6)15(19)14(11-12)18(7,8)9/h10-11H,1-9H3
InChI key	JOKZWHPYNRDCOA-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

1-Bromo-2,4,6-tri-tert-butylbenzene

1-溴-2,4,6-三叔丁基苯