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Garg 4,5-indolyne precursor

品牌
Sigma-Aldrich
CAS
1259448-37-7
货号
795569
包装型号
规格纯度
95%
参考价格
2198.43 *本价格含增值税费
促销
服务
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数量
-+
产品名称:
1259448-37-7
Garg 4,5-indolyne precursor
4-(Trimethylsilyl)-1H-indol-5-yl trifluoromethanesulfonate
产品介绍:

产品说明

一般描述

Garg 4,5-indolyne precursor is an indolyne precursor developed by Professor Neil Garg and coworkers. It is widely used for the synthesis of various N-heterocyclic based compounds. It is also useful for the preparation of substituted indoles (Diels–Alder and azide cycloaddition products).

应用

Indolyne precursor can be activated under mild fluoride conditions, which are highly reactive with dienes and other dipolariphiles (e.g. azides) to provide cycloaddition products containing an indole motif.

包装

1 g in glass bottle

其他说明

Indolyne Experimental and Computational Studies: Synthetic Applications and Origins of Selectivities of Nucleophilic Additions
Regioselective reactions of 3; 4-pyridynes enabled by the aryne distortion model

基本信息

经验(实验)分子式C12H14F3NO3SSi
分子量337.39
MDL编号MFCD25976536
PubChem化学物质编号329768491
NACRESNA.22

产品性质

质量水平100
测定95%
mp43-48 ℃
储存温度2-8℃
SMILES stringO=S(OC1=C([Si](C)(C)C)C2=C(NC=C2)C=C1)(C(F)(F)F)=O
InChI1S/C12H14F3NO3SSi/c1-21(2,3)11-8-6-7-16-9(8)4-5-10(11)19-20(17,18)12(13,14)15/h4-7,16H,1-3H3
InChI keyLLCJFYYASDIOJN-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

Sigma-Aldrich

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