(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)

产品名称：

259259-80-8
(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
(S,S)-AMAC
(1S,2S)-N,N′-双(2-乙酰-3-氧代-2-亚丁烯基)-1,2-二均三甲苯基乙二胺合钴(II)

产品介绍：

产品说明

应用

Catalyst for:

Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene
Enantioselective borohydride reduction
Preparation of ß-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases
Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones

包装

100, 500 mg in amber glass bottle

基本信息

经验(实验)分子式	C₃₂H₃₈CoN₂O₄
分子量	573.59
MDL编号	MFCD06797062
PubChem化学物质编号	329762829
NACRES	NA.22

产品性质

质量水平	100
形式	solid
旋光性	[α]/D −309°, c = 0.1 in chloroform
mp	242-246 ℃
SMILES string	CC(=O)C1=C(C)O[Co]OC(C)=C(\C=N\[C@H]([C@@H](\N=C\1)c2c(C)cc(C)cc2C)c3c(C)cc(C)cc3C)C(C)=O
InChI	1S/C32H40N2O4.Co/c1-17-11-19(3)29(20(4)12-17)31(33-15-27(23(7)35)24(8)36)32(34-16-28(25(9)37)26(10)38)30-21(5)13-18(2)14-22(30)6;/h11-16,31-32,35,37H,1-10H3;/q;+2/p-2/b27-23+,28-25+,33-15+,34-16+;/t31-,32-;/m0./s1
InChI key	PHCQQLMRNZRDJA-OZXAGROVSA-L

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)