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位置:首页 > 品牌 > Sigma-Aldrich > (1S,2S)-N,N′-双(2-乙酰-3-氧代-2-亚丁烯基)-1,2-二均三甲苯基乙二胺合钴(II)

(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)

(1S,2S)-N,N′-双(2-乙酰-3-氧代-2-亚丁烯基)-1,2-二均三甲苯基乙二胺合钴(II)

品牌
Sigma-Aldrich
CAS
259259-80-8
货号
708844
包装型号
规格纯度
参考价格
748.23 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
-+
产品名称:
259259-80-8
(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
(S,S)-AMAC
(1S,2S)-N,N′-双(2-乙酰-3-氧代-2-亚丁烯基)-1,2-二均三甲苯基乙二胺合钴(II)
产品介绍:

产品说明

应用

Catalyst for:

  • Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene
  • Enantioselective borohydride reduction
  • Preparation of ß-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases
  • Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones

包装

100, 500 mg in amber glass bottle

基本信息

经验(实验)分子式C32H38CoN2O4
分子量573.59
MDL编号MFCD06797062
PubChem化学物质编号329762829
NACRESNA.22

产品性质

质量水平100
形式solid
旋光性[α]/D −309°, c = 0.1 in chloroform
mp242-246 ℃
SMILES stringCC(=O)C1=C(C)O[Co]OC(C)=C(\C=N\[C@H]([C@@H](\N=C\1)c2c(C)cc(C)cc2C)c3c(C)cc(C)cc3C)C(C)=O
InChI1S/C32H40N2O4.Co/c1-17-11-19(3)29(20(4)12-17)31(33-15-27(23(7)35)24(8)36)32(34-16-28(25(9)37)26(10)38)30-21(5)13-18(2)14-22(30)6;/h11-16,31-32,35,37H,1-10H3;/q;+2/p-2/b27-23+,28-25+,33-15+,34-16+;/t31-,32-;/m0./s1
InChI keyPHCQQLMRNZRDJA-OZXAGROVSA-L

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)

Sigma-Aldrich

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