产品说明
应用
Potassium acyltrifluroborates(KAT′s) are bench, air and moisture stable reagents for rapid, chemoselective amide bond formations with hydroxylamines. These amide bond forming reactions proceed under aqueous conditions, without the need for coupling reagents or protecting groups. This product was introduced in collaboration with the Bode Research Group.
包装
1 g in glass bottle
其他说明
Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate(KAT) Amide Formation
Synthesis of Chemically and Configurationally Stable Monofluoro Acylboronates: Effect of Ligand Structure on their Formation, Properties, and Reactivities
Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water
基本信息
| 经验(实验)分子式 | C8H4BF3KNO |
| 分子量 | 237.03 |
| PubChem化学物质编号 | 329768906 |
| NACRES | NA.22 |
产品性质
| 形式 | powder |
| 质量水平 | 100 |
| mp | 252-257 ℃ (decomp, no melt) |
| SMILES string | O=C(B(F)(F)F)C1=CC=C(C#N)C=C1.[K] |
| InChI | 1S/C8H4BF3NO.K.H/c10-9(11,12)8(14)7-3-1-6(5-13)2-4-7;;/h1-4H;; |
| InChI key | GOGQLWPRIKMEND-UHFFFAOYSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H315 - H319 - H335 |
| 预防措施声明 | P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
Sigma-Aldrich
m.cnreagent.com
