(2<I>R</I>)-(+)-3,3′-二苯基-[2,2′-联二萘]-1,1′-二醇

产品名称：

147702-13-4
(R)-VANOL
(R)-3,3′-Diphenyl-2,2′-bi-1-naphthalol
(R)-3,3′-Diphenyl-2,2′-bi-1-naphthol
(R)-3,3′-二苯基-2,2′-二-1-萘酚
(2R)-(+)-3,3′-二苯基-[2,2′-联二萘]-1,1′-二醇

产品介绍：

产品说明

应用

已证实 VANOL 是用于催化型不对称 Diels-Alder 反应、亚胺羟醛反应以及氮杂环丙化反应的绝佳配体。
(R)-VANOL is a vaulted biaryl ligand that may be used in the following processes:

Transformation of 3-substituted cyclobutanones to enantiopure γ-butyrolactones via asymmetric Baeyer-Villiger Reaction in the presence of an aluminum catalyst.
Asymmetric aziridination of N-(4-(Methylsulfonyl)benzylidene)diphenylmethanamine to form (2S,3S)-ethyl 1-benzhydryl-3-(4-(methylsulfonyl)phenyl) aziridine-2-carboxylate.
Conjugate addition of terminal alkynes to 2-arylidene-1,3-diketones with high enantioselectivity in the presence of diethyl zinc.

包装

250 mg in amber glass bottle

基本信息

经验(实验)分子式	C₃₂H₂₂O₂
分子量	438.52
MDL编号	MFCD08459338
PubChem化学物质编号	24885264
NACRES	NA.22

产品性质

测定	97%
旋光性	[α]20/D +310°, c = 1 in chloroform
mp	200-204 ℃
SMILES string	Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6
InChI	1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H
InChI key	NDTDVKKGYBULHF-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H315 - H318 - H335 - H413
预防措施声明	P273 - P280 - P302 + P352 - P305 + P351 + P338 + P310
危险分类	Aquatic Chronic 4 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves