二氯[(<I>S</I>)-(-)-2,2′-二[二(3,5-二甲苯基)膦基]-1,1′-联萘基][(2<I>S</I>)-(+)-1,1-二(4-甲氧苯基)-3-甲基-1,2-丁二胺]钌(II)

产品名称：

220114-01-2
RuCl₂[(S)-(DM-BINAP)][(S)-DAIPEN]
Dichloro[(S)-(-)-2,2′-bis[di(3,5-xylyl)phosphino]-1,1′-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
二氯[(S)-(-)-2,2′-二[二(3,5-二甲苯基)膦基]-1,1′-联萘基][(2S)-(+)-1,1-二(4-甲氧苯基)-3-甲基-1,2-丁二胺]钌(II)

产品介绍：

产品说明

应用

Catalyst for:

Preparation of cyclometalated ruthenium 1,1-dianisyl-2-isopropyl-1,2-ethylenediamine complexes via asymmetric hydrogenation of ketones
Enantioselective hydrogenation of an α-alkoxy substituted ketone with chiral ruthenium (phosphinoferrocenyl)oxazoline complexes
Nonclassical asymmeteric hydrogen transfer between alcohols and carbonyl compounds
Asymmetric hydrogenation of amino and heteroaromatic ketones

Pharmacologically active substituted oxazolidinone used as NPC1L1 ligand for inhibition of cholesterol absorption

Takasago Ligands and Complexes for Asymmetric Reactions

包装

50, 100 mg in amber glass bottle

法律信息

与 Takasago 合作销售，仅用于研究目的。日本注册号 041996, 2731377, 2935453，日本申请号19970359654

基本信息

经验(实验)分子式	C₇₁H₇₄Cl₂N₂O₂P₂Ru
分子量	1221.28
PubChem化学物质编号	329761574
NACRES	NA.22

产品性质

形式	powder
质量水平	100
储存温度	2-8℃
SMILES string	COc1ccc(cc1)C2([NH2][Ru]3(Cl)(Cl)([NH2][C@H]2C(C)C)[PH](c4cc(C)cc(C)c4)(c5cc(C)cc(C)c5)c6ccc7ccccc7c6-c8c(ccc9ccccc89)[PH]3(c%10cc(C)cc(C)c%10)c%11cc(C)cc(C)c%11)c%12ccc(OC)cc%12
InChI	1S/C52H48P2.C19H26N2O2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-11-17(23-4)12-8-15;;;/h9-32H,1-8H3;5-13,18H,20-21H2,1-4H3;2*1H;/t;18-;;;/m.0.../s1
InChI key	VMSNEARTLSFOHB-OGLOXHGMSA-N

RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN]

Dichloro[(S)-(-)-2,2′-bis[di(3,5-xylyl)phosphino]-1,1′-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

RuCl₂[(S)-(DM-BINAP)][(S)-DAIPEN]