二羰基氯[(1,2,3,4,5,-η)-1,2,3,4,5-五苯基环-2,4-戊二烯-1-基)]钌

产品名称：

677736-23-1
Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
Dicarbonylchloro[(1,2,3,4,5,-η)-1,2,3,4,5-pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium
氯二羰基(1,2,3,4,5-五苯基环戊二烯基)钌(II)
二羰基氯[(1,2,3,4,5,-η)-1,2,3,4,5-五苯基环-2,4-戊二烯-1-基)]钌

产品介绍：

产品说明

应用

Reactant for:

Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst
Ligand exchange
Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds

Catalyst for:

(S)-Selective dynamic kinetic resolution of secondary alcohols
Stereoselective synthesis of neonicorinoide pesticide derivatives
Divergent asymmetric synthesis of 3,5-disubstituted piperidines

包装

1 g in glass bottle
250 mg in glass bottle

引用

用于与酶共同作用，通过动态动力学拆分来催化不对称转化的金属催化剂

法律信息

Kanata Chemical Technologies, Inc. 产品

基本信息

经验(实验)分子式	C₃₇H₂₅ClO₂Ru
分子量	638.12
MDL编号	MFCD09265041
PubChem化学物质编号	329761049
NACRES	NA.22

产品性质

质量水平	100
reaction suitability	core: ruthenium reagent type: catalyst
mp	152-167 ℃
SMILES string	Cl[Ru].[C-]#[O+].[C-]#[O+].c1ccc(cc1)[C]2[C]([C]([C]([C]2c3ccccc3)c4ccccc4)c5ccccc5)c6ccccc6
InChI	1S/C35H25.2CO.ClH.Ru/c1-6-16-26(17-7-1)31-32(27-18-8-2-9-19-27)34(29-22-12-4-13-23-29)35(30-24-14-5-15-25-30)33(31)28-20-10-3-11-21-28;2*1-2;;/h1-25H;;;1H;/q;;;;+1/p-1
InChI key	NGSBLRJKXUHTOC-UHFFFAOYSA-M

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves